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    • https://phys.libretexts.org/Bookshelves/Quantum_Mechanics/Introductory_Quantum_Mechanics_(Fitzpatrick)/12%3A_Time-Dependent_Perturbation_Theory/12.13%3A_Forbidden_Transitions
      Expanding exp(ikr), and keeping the first two terms, the matrix element for a forbidden transition becomes \[\label{e13.146} \langle f|\epsilon\!\cdot\!{\bf p}\,\ex...Expanding exp(ikr), and keeping the first two terms, the matrix element for a forbidden transition becomes f|ϵpexp(ikr)|iif|(ϵp)(kr)|i. Hence, if the residual matrix element on the right-hand side of the previous expression is non-zero then a “forbidden” transition can take place, albeit at a mu…

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