3.1: Schrodinger's Equation
( \newcommand{\kernel}{\mathrm{null}\,}\)
Consider a dynamical system consisting of a single non-relativistic particle of mass m moving along the x-axis in some real potential V(x). In quantum mechanics, the instantaneous state of the system is represented by a complex wavefunction \psi(x,t). This wavefunction evolves in time according to Schrödinger’s equation: \label{e3.1} {\rm i}\,\hbar\,\frac{\partial\psi}{\partial t} = -\frac{\hbar^{\,2}}{2\,m}\frac{\partial^{\,2} \psi}{\partial x^{\,2}} + V(x)\,\psi. The wavefunction is interpreted as follows: |\psi(x,t)|^{\,2} is the probability density of a measurement of the particle’s displacement yielding the value x. Thus, the probability of a measurement of the displacement giving a result between a and b (where a<b) is \label{e3.2} P_{x\,\in\, a:b}(t) = \int_{a}^{b}|\psi(x,t)|^{\,2}\,dx. Note that this quantity is real and positive definite.