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    • https://phys.libretexts.org/Bookshelves/Thermodynamics_and_Statistical_Mechanics/Essential_Graduate_Physics_-_Statistical_Mechanics_(Likharev)/04%3A_Phase_Transitions/4.01%3A_First_order_phase_transitions
      One advantage of this simple model is that in the rare gas limit, \(Nb << V\), it reduces back to the microscopically-justified Equation (\ref{1}). (To verify this, it is sufficient to Taylor-expand t...One advantage of this simple model is that in the rare gas limit, \(Nb << V\), it reduces back to the microscopically-justified Equation (\ref{1}). (To verify this, it is sufficient to Taylor-expand the right-hand side of Equation (\ref{2}) in small \(Nb/V << 1\), and retain only two leading terms.) Let us explore the basic properties of this model.

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