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    • https://phys.libretexts.org/Bookshelves/Thermodynamics_and_Statistical_Mechanics/Book%3A_Thermodynamics_and_Statistical_Mechanics_(Arovas)/04%3A_Statistical_Ensembles/4.08%3A_Selected_Examples
      Calculate the fraction \(f\) of occupied adsorption sites as a function of the gas density \(n\), the temperature \(T\), the binding energy \(\RDelta\), and physical constants. Since the surface is in...Calculate the fraction \(f\) of occupied adsorption sites as a function of the gas density \(n\), the temperature \(T\), the binding energy \(\RDelta\), and physical constants. Since the surface is in equilibrium with the gas, its fugacity \(z=\exp(\mu/\kT)\) and temperature \(T\) are the same as in the gas. At \(\tau=0\) the A state is preferred for each monomer, but when \(\tau\) exceeds \(\tau^*\), defined by the relation \(\vet\subA=\vet\subB\), the B state is preferred.

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