In the photoelectric effect, incoming light causes an atom to eject an electron. We consider the simplest possible scenario: that the atom is hydrogen in its ground state. The interesting question is:...In the photoelectric effect, incoming light causes an atom to eject an electron. We consider the simplest possible scenario: that the atom is hydrogen in its ground state. The interesting question is: for an ingoing light wave of definite frequency and amplitude, what is the probability of ionization of a hydrogen atom in a given time? In other words, assuming we can use time-dependent perturbation theory, what is the ionization rate?