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Physics LibreTexts

11.6: Curve of Growth for Voigt Profiles

( \newcommand{\kernel}{\mathrm{null}\,}\)

Our next task is to construct curves of growth for Voigt profiles for different values of the ratio of the lorentzian and gaussian HWHMs, l/g, which is

lg=Γλ04πVmln2=Γλ0Vmπln65536=Γλ034.841Vm,

or, better, for different values of the gaussian ratio kG=gl+g. These should look intermediate in appearance between figures XI.3 and 5.

The expression for the equivalent width in wavelength units is given by Equation 11.3.4:

W=20[1exp{τ(x)}]dx.

combined with Equation 10.5.20

τ(x)=Clτ(0)exp[(ξx)2ln2/g2]ξ2+l2dξ.

That is:

W=20(1exp{Clτ(0)exp[(ξx)2ln2/g2]ξ2+l2dξ})dx.

Here

  • x=λλ0, l is the Lorentzian HWHM=λ20Γ/(4πc) (where Γ may include a pressure-broadening contribution),
  • g is the gaussian HWHM=Vmλ0ln2/c (where Vm may include a microturbulence contribution), and
  • W is the equivalent width, all of dimension L.

The symbol ξ, also of dimension L, is a dummy variable, which disappears after the definite integration. τ(0) is the optical thickness at the line centre. C is a dimensionless number given by Equation 10.5.23 and tabulated as a function of gaussian fraction in Chapter 10. The reader is urged to check the dimensions of Equation 11.6.2 carefully. The integration of Equation 11.6.2 is discussed in Appendix A.

Our aim is to calculate the equivalent width as a function of τ(0) for different values of the gaussian fraction kG=g/(l+g). What we find is as follows. Let W=Wln2/g; that is, W is the equivalent width expressed in units of g/ln2. For τ(0) less than about 5, where the wings contribute relatively little to the equivalent width, we find that W is almost independent of the gaussian fraction. The difference in behaviour of the curve of growth for different profiles appears only for large values of τ(0), when the wings assume a larger role. However, for any profile which is less gaussian than about kG equal to about 0.9, the behaviour of the curve of growth (for τ(0)>5) mimics that for a lorentzian profile. For that reason I have drawn curves of growth in figure XI.6 only for kG=0.9,0.99,0.999 and 1. This corresponds to l/g=0.1111,0.0101,0.0010 and 0, or to Γλ0/Vm=1.162,0.1057,0.0105 and 0 respectively.

alt
FIGURE XI.6


This page titled 11.6: Curve of Growth for Voigt Profiles is shared under a CC BY-NC 4.0 license and was authored, remixed, and/or curated by Jeremy Tatum via source content that was edited to the style and standards of the LibreTexts platform.

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