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0.1: Math and Measurements

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    128557
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    Numbers in Astronomy

    Use reassuring language - toolkit includes a lot of calculations and equations - they are there for anyone that wants to see them, you do not have to memorize them or be able to replicate the calculations to understand the rest of the textbook.  Different teachers/classes may adjust the math level

    Big numbers,

    equations- variables, proportionality

    measurements - metric and dimensions

      - light years

     

    Written for classes with no math pre-requisite

    Will include equations, example exercises. math problems using algebra?

    Next section:

    1. velocity m/s
    2. acceleration/gravity m/s2

    Practice unit conversions - dimension analysis?

    how should i format math, with Tex or html?

    . First, we use a system for writing large and small numbers called scientific notation. This system eliminates the many zeros of very large or very small numbers. In scientific notation, if you want to write a number such as 500,000,000, you express it as 5 x 108. This also works for very small numbers by using a negative number in the exponent. In this way, 0.00000003 can be represented as 3 x 10-8.

    A common unit astronomers use to describe distances in the universe is a light-year, which is the distance light travels during one year. Even though it has year in its name, it does not measure time. Because light always travels at the same speed, it makes a good standard for keeping track of distances. The speed of light is 3 x 105 km/s and a light year is 9.5 x 1012 km.

    There is another reason the speed of light is such a natural unit of distance for astronomers. Information about the universe comes to us almost exclusively through various forms of light, and all such light travels at the speed of light. This sets a limit on how quickly we can learn about events in the universe. If a star is 100 light-years away, the light we see from it tonight left that star 100 years ago. If anything happened to the star between the time the light left the star and now, we won't know until the event is 100 years old.

    What at first may seem a challenge is actually a tremendous benefit in disguise. If astronomers really want to piece together what has happened in the universe since its beginning, they need some kind of data from the past. Fortunately, the farther out in space we look, the longer the light has taken to get here. By looking billions of light-years out into space, astronomers are actually seeing billions of years into the past. In this way, we can reconstruct the history of the cosmos and get a sense of how it has evolved over time.

    This is one reason why astronomers strive to build telescopes that can collect more and more of the faint light in the universe. The more light we collect, the fainter the objects we can observe. On average, fainter objects are farther away and can, therefore, tell us about periods of time even deeper in the past. As each new telescope comes online, astronomers are able to see farther into the past.

    Scientific Notation

    Scientific notation is used to express very large and very small numbers as a product of two numbers. The first number of the product, the digit term, is usually a number not less than 1 and not greater than 10. The second number of the product is the exponential term. An exponential term is written with 2 separate numbers, the base and the exponent. An example with 6 as the base and 3 as the exponent is written 63. The value of the exponent is the number of times to multiply the base times itself, so 63=6×6×6=216. In scientific notation the base is always 10. A number in scientific notation with a digit term of 2.45 and an exponential term of \(10^6\) is written \(2.45×10^6\). Some examples of scientific notation are:

    \[\begin{align*}
    1000&=1×10^3\\
    100&=1×10^2\\
    10&=1×10^1\\
    1&=1×10^0\\
    0.1&=1×10^{−1}\\
    0.001&=1×10^{−3}\\
    2386&=2.386×1000=2.386×10^3\\
    0.123&=1.23×0.1=1.23×10^{−1}
    \end{align*} \nonumber \]

    Scientific notation is also called powers of 10 notation. Note that 102 also designates or 10 × 10, which equals 100. And 9.65 × 100 is just 965. Another way to look at scientific notation is that we separate out the complicated numbers out front, and leave the units of ten to indicate the size of the number. This means that the digit term only ever has one number to the left of the decimal point. So a number like 1,372,568 becomes 1.372568 times a million (106) or \(1.372568×10^6\). The value of the exponent is also the number of times that the decimal point (.) is moved. If we include the decimal point in the above number, it would be 1,372,568. with the decimal point after the 8. We had to move the decimal point six places to the left to get the number into the form where there is only one digit to the left of the decimal point. The reason we call this powers-of-ten notation is that our counting system is based on increases of ten; each place in our numbering system is ten times greater than the place to the right of it.

    Very Large Numbers

    In astronomy (and other sciences), it is often necessary to deal with very large numbers. Among the measurements astronomers must routinely deal with is that the Earth is 150,000,000,000 meters from the Sun. Some numbers in astronomy are even larger, and would be hard to write out and difficult to read. Since the base of the exponential term is always 10, for exponents that have a positive value, the exponent is the number of zeroes after the 1. For example, \(10^11=100,000,000,000\) or a 1 with 11 zeroes after it. The distance from the Sun to the Earth can also be written .

    So, in the example we started with, the number of meters from Earth to the Sun is \(1.5×10^11\). Elsewhere in the book, we mention that a string 1 light-year long would fit around Earth’s equator 236 million or 236,000,000 times. In scientific notation, this would become 2.36 × 108. Now if you like expressing things in millions, as the annual reports of successful companies do, you might like to write this number as 236 × 106. However, the usual convention is to have only one number to the left of the decimal point.

    Very Small Numbers

    Astronomy involves very small numbers, such as the mass of the hydrogen atom, 0.00000000000000000000000000167 kilograms. For very small numbers, the exponent is a negative number, such as -10. For negative exponents, the total number of zeroes is still the same, but all of the zeroes are in front of the one and the decimal point (.) is placed between the first and second zero and 0.00000000036 = 3.6 × 10−10.

    Now take a number like 0.00347, which is also not in the standard (agreed-to) form for scientific notation. To put it into that format, we must make the first part of it 3.47 by moving the decimal point three places to the right. Note that this motion to the right is the opposite of the motion to the left that we discussed above. To keep track, we call this change negative and put a minus sign in the exponent. Thus 0.00347 becomes 3.47 × 10−3.

    In the example we gave at the beginning, the mass of the hydrogen atom would then be written as 1.67 × 10−27 kg. In this system, one is written as 100, a tenth as 10−1, a hundredth as 10−2, and so on. Note that any number, no matter how large or how small, can be expressed in scientific notation.

    Measurements in Science

    Numerical values for physical quantities are required to study the universe. To comprehend these vast ranges, we must also have accepted units in which to express them. For example, to measure distance and time scientists define specific units to measure them. Measurements of physical quantities are expressed in terms of units, which are standardized values. For example, the length of a race, which is a physical quantity, can be expressed in units of meters or kilometers. Without standardized units, it would be extremely difficult for scientists to express and compare measured values in a meaningful way. Units, such as liters, pounds, and centimeters, are standards of comparison for measurements. A 2-liter bottle of a soft drink contains a volume of beverage that is twice that of the accepted volume of 1 liter.

    The SI Units

    The acronym “SI” is derived from the French Système International. In science, measurements use the metric system,. Its great advantage is that every unit increases by a factor of ten. For example, in the metric system there are 10 millimeters in one centimeter.

    For this textbook, we will start with four base units that are listed in Table \(\PageIndex{1}\). These base units are measurements of length, mass, time, and temperature. The standards for these units are fixed by international agreement. SI units have been used by the United States National Institute of Standards and Technology (NIST) since 1964. Units for other properties, such as volume and and density, may be derived from these base units. The base unit of mass is unique in that a decimal prefix, a term defined in the next section, is included. That is, it is the kilogram, not the gram, as you might expect. The base unit of time is the only one that is not metric. Numerous attempts to make it so have never garnered any success; we are still stuck with the 24:60:60 system that we inherited from ancient times.

    Table \(\PageIndex{1}\): SI base units
    Observable Base Unit Abbreviation
    length meter m
    mass kilogram kg
    time second s
    temperature (absolute) Kelvin K

    The SI Decimal Prefixes

    Metric systems have the advantage that conversions of units involve only powers of 10, or order of magnitude. There are 100 centimeters in a meter, 1000 meters in a kilometer, and so on. Another advantage of the metric system is that the same unit can be used over extremely large ranges of values simply by using an appropriate decimal prefix, listed in Table \(\PageIndex{2}\). For example, distances in meters are suitable in construction, while distances in kilometers are appropriate for air travel, and the tiny measure of nanometers are convenient in optical design. With the metric system there is no need to invent new units for particular applications.

    In this textbook, we will be discussing events that occurred a billion years ago, which can also be written 109 years, or 1 Gyr, which is read one giga-year. We will also mention objects that are so small that they must be measured in in nanometers (nm). There is no need to memorize this entire list. Instead use it, or one like it to help understand the scale of a measurement.

    Table \(\PageIndex{2}\): SI Decimal Prefixes
    Prefix Symbol Value Example (some are approximate)
    exa E

    1018

    exameter Em

    1018 m

    distance light travels in a century
    peta P

    1015

    petasecond Ps

    1015 s

    30 million years
    tera T

    1012

    terawatt TW

    1012 W

    powerful laser output
    giga G

    109

    gigahertz GHz

    109 H

    a microwave frequency
    mega M

    106

    megacurie MCi

    106 C

    high radioactivity
    kilo k

    103

    kilometer km

    103 m

    about 6/10 mile
    hecto h

    102

    hectoliter hL

    102 L

    26 gallons
    deka da

    101

    dekagram dag

    101 g

    teaspoon of butter

    100

    (=1)

           
    deci d

    10−1

    deciliter dL

    10−1 L

    less than half a soda
    centi c

    10−2

    centimeter cm

    10−2 m

    fingertip thickness
    milli m

    10−3

    millimeter mm

    10−3 m

    flea at its shoulders
    micro µ

    10−6

    micrometer µm

    10−6 m

    detail in microscope
    nano n

    10−9

    nanogram ng

    10−9 g

    small speck of dust
    pico p

    10−12

    picofarad pF

    10−12 F

    small capacitor in radio
    femto f

    10−15

    femtometer fm

    10−15 m

    size of a proton
    atto a

    10−18

    attosecond as

    10−18 s

    time light crosses an atom

    The Base Units

    There are technically seven base units, but to simplify things we are limiting ourselves to the ones we are using in this textbook: length, mass, time, and temperature. If you want to learn about amount of material, in moles, electric current, or luminous intensity, you can visit the NIST website included in the Further Exploration box at the end of this page.

    Length

    The standard unit of length in both the SI system is the meter (m). A meter was originally specified as 1/10,000,000 of the distance from the North Pole to the equator. It is now defined as the distance light in a vacuum travels in 1/299,792,458 of a second. A meter is about 3 inches longer than a yard (Figure \(\PageIndex{1}\)); one meter is about 39.37 inches or 1.094 yards. Longer distances are often reported in kilometers (1 km = 1000 m = 103 m), whereas shorter distances can be reported in centimeters (1 cm = 0.01 m = 10−2 m) or millimeters (1 mm = 0.001 m = 10−3 m). To convert from the American system, here are a few helpful factors: 1 mile is 1.61 kilometers (km) and 1 inch is 2.54 centimeters (cm).

    Mass

    Roughly speaking, mass is a measure of the amount of matter in something. The quantity or amount of matter in an object is determined by the numbers of atoms and molecules of various types it contains. Unlike weight, mass does not vary with location. The mass of an object is the same on Earth, in orbit, or on the surface of the Moon. In practice, it is very difficult to count and identify all of the atoms and molecules in an object, so masses are not often determined in this manner. The SI unit for mass is the kilogram (kg). It is currently defined to be the mass of a platinum-iridium cylinder kept with the old meter standard at the International Bureau of Weights and Measures near Paris. Exact replicas of the standard kilogram are also kept at the United States’ National Institute of Standards and Technology, or NIST, located in Gaithersburg, Maryland outside of Washington D.C., and at other locations around the world. The determination of all other masses can be ultimately traced to a comparison with the standard mass. At the November 2018 meeting of the International Committee for Weights and Measures, a proposed re-definition of kilogram was approved. This proposal (effective May 2019) re-defines the kilogram by precisely fixing the numerical value of Planck's constant (hh) to be exactly 6.62607015 x 10-34 kg m2 s-1. This is similar to definition of the meter by fixing the speed of light.

    A weight of 1 lb is equivalent on Earth to a mass of 0.4536 kg, while a weight of 1 oz is produced by a mass of 28.35 g. Although weight is related to mass, it is not the same thing. Weight refers to the force that gravity exerts on an object. This force is directly proportional to the mass of the object. The weight of an object changes as the force of gravity changes, but its mass does not. An astronaut’s mass does not change just because she goes to the moon. But her weight on the moon is only one-sixth her earth-bound weight because the moon’s gravity is only one-sixth that of the earth’s.

    Time

    The SI unit for time, the second (s), has a long history. For many years it was defined as 1/86,400 of a mean solar day. More recently, a new standard was adopted to gain greater accuracy and to define the second in terms of a non-varying, or constant, physical phenomenon because the solar day is getting longer due to very gradual slowing of the Earth’s rotation. Cesium atoms can be made to vibrate in a very steady way, and these vibrations can be readily observed and counted using an atomic clock. In 1967 the second was redefined as the time required for 9,192,631,770 of these vibrations. Accuracy in the fundamental units is essential, because all measurements are ultimately expressed in terms of fundamental units and can be no more accurate than are the fundamental units themselves.

    Temperature

    The concept of temperature has evolved from the common concepts of hot and cold. In science, heat is the quantity of thermal energy that enters or leaves a body. Meanwhile, temperature measures the average translational kinetic energy of the molecules in a body. Since it is challenging to measure the average speed of a molecule, temperature  is operationally defined to be what we measure with a thermometer.

    Thermometers are used to measure temperature according to well-defined scales of measurement, which use pre-defined reference points to help compare quantities. A temperature scale can be created by identifying two easily reproducible temperatures, usually the freezing and boiling temperatures of water at standard atmospheric pressure. The SI unit of temperature is the kelvin (K). Note that temperatures in Kelvin are a number an the letter K, without a degree symbol (°), such as 275 K. The degree Celsius (°C) is also allowed in the SI system, with both the word degree and the degree symbol used for Celsius measurements. Celsius degrees are the same magnitude as those of kelvin, but the two scales place their zeros in different places. Water freezes at 273.15 K (0 °C) and boils at 373.15 K (100 °C). All molecular motion ceases at about −459 °F = −273 °C = 0 K, a temperature called absolute zero. Kelvin temperature is measured from this lowest possible temperature, and it is the temperature scale most often used in astronomy All three temperature scales are included in Figure \(\PageIndex{1}\) along with the boiling and freezing points of water and absolute zero.

    alt-text
    Figure \(\PageIndex{1}\): Temperature Scales. The Kelvin, Celsius, and Fahrenheit are all tired to the freezing and boiling points of water. (CC0[ccol]; Emeka Udenze[https://commons.wikimedia.org/wiki/U...ekadecatalyst] via wc)

    Converting between Celsius and Fahrenheit is easy if you bear in mind that between the freezing and boiling points of water there are 180 Fahrenheit degrees, but only 100 Celsius degrees, making the F° 100/180 = 5/9 the magnitude of the C°. Because the freezing point is at 32 °F, the two scales are offset by this amount.

    The full conversion formulas are:

    • K = °C + 273
    • °C = 0.555 × (°F – 32)
    • °F = (1.8 × °C) + 32

    To convert to Kelvin, since 0 °C = 273 K, add 273 to the temperature in Celsius. For example, 25 °C is 298 K.

    Derived SI Units

    We can derive many units from the seven SI base units. For example, we can use the base unit of length to define a unit of volume, and the base units of mass and length to define a unit of density.

    Properties of Matter

    The science of chemistry developed from observations made about the nature and behavior of different kinds of matter, which we refer to collectively as the properties of matter. The properties we refer to in this lesson are all macroscopic properties: those that can be observed in bulk matter. At the microscopic level, matter is of course characterized by its structure: the spatial arrangement of the individual atoms in a molecular unit or an extended solid. By observing a sample of matter and measuring its various properties, we gradually acquire enough information to characterize it; to distinguish it from other kinds of matter. This is the first step in the development of chemical science, in which interest is focused on specific kinds of matter and the transformations between them.

    If you think about the various observable properties of matter, it will become apparent that these fall into two classes. Some properties, such as mass and volume, depend on the quantity of matter in the sample we are studying. Clearly, these properties, as important as they may be, cannot by themselves be used to characterize a kind of matter; to say that “water has a mass of 2 kg” is nonsense, although it may be quite true in a particular instance. Properties of this kind are called extensive properties of matter.

    Suppose we take further measurements, and find that the same quantity of water whose mass is 2.0 kg also occupies a volume of 2.0 liters. We have measured two extensive properties (mass and volume) of the same sample of matter. This allows us to define a new quantity, the quotient m/V which defines another property of water which we call the density. Unlike the mass and the volume, which by themselves refer only to individual samples of water, the density (mass per unit volume) is a property of all samples of pure water at the same temperature. Density is an example of an intensive property of matter.

    This definition of the density illustrates an important general rule: the ratio of two extensive properties is always an intensive property.

    Intensive properties are extremely important, because every possible kind of matter possesses a unique set of intensive properties that distinguishes it from every other kind of matter. Some intensive properties can be determined by simple observations: color (absorption spectrum), melting point, density, solubility, acidic or alkaline nature, and density are common examples. Even more fundamental, but less directly observable, is chemical composition.

    The more intensive properties we know, the more precisely we can characterize a sample of matter.

    Intensive properties are extremely important, because every possible kind of matter possesses a unique set of intensive properties that distinguishes it from every other kind of matter. In other words, intensive properties serve to characterize matter. Many of the intensive properties depend on such variables as the temperature and pressure, but the ways in which these properties change with such variables can themselves be regarded as intensive properties.

    Table 3.1: Densities of Common Materials
    Material Density (g/cm3)
    Gold 19.3
    Lead 11.3
    Iron 7.9
    Earth (bulk) 5.5
    Rock (typical) 2.5
    Water 1
    Wood (typical) 0.8
    Insulating foam 0.1
    Silica gel 0.02

    To sum up, mass is how much, volume is how big, and density is how tightly packed.

    Volume

    Volume is the measure of the amount of space occupied by an object. The standard SI unit of volume is defined by the base unit of length. The standard volume is a cubic meter (m3), a cube with an edge length of exactly one meter. To dispense a cubic meter of water, we could build a cubic box with edge lengths of exactly one meter. This box would hold a cubic meter of water or any other substance, as shown in (Figure \(\PageIndex{2}\)).

    Figure \(\PageIndex{2}\): Volume. (a) The relative volumes are shown for cubes of 1 m3, 1 dm3 (1 L), and 1 cm3 (1 mL) (not to scale). (b) The diameter of a dime is compared relative to the edge length of a 1-cm3 (1-mL) cube. (Openstax Chemistry)

    Density

    A penny and an inflated balloon may both have the same mass, but they have very different volumes. The reason is that they also have very different densities, which is a measure of how much mass there is per unit volume. Specifically, density is the mass divided by the volume. Note that in everyday language we often use “heavy” and “light” as indications of density (rather than weight) as, for instance, when we say that iron is heavy or that whipped cream is light.

    While there are many ways to determine the density of an object, perhaps the most straightforward method involves separately finding the mass and volume of the object, and then dividing the mass of the sample by its volume. In the following example, the mass is found directly by weighing, but the volume is found indirectly through length measurements.

    \[\text { density }=\frac{\text { mass }}{\text { volume }}\]

    The units of density that will be used in this book are grams per cubic centimeter (g/cm3). If a block of some material has a mass of 300 grams and a volume of 100 cm3, its density is 3 g/cm3. Familiar materials span a considerable range in density, from artificial materials such as plastic insulating foam (less than 0.1 g/cm3) to gold (19.3 g/cm3). Table 3.1 gives the densities of some familiar materials. In the astronomical universe, much more remarkable densities can be found, all the way from a comet’s tail (10-16 g/cm3) to a collapsed “star corpse” called a neutron star (1015 g/cm3).

    The density of a substance is the ratio of the mass of a sample of the substance to its volume. The SI unit for density is the kilogram per cubic meter (kg/m3). For many situations, however, this is an inconvenient unit, and we often use grams per cubic centimeter (g/cm3) for the densities of solids and liquids, and grams per liter (g/L) for gases. Although there are exceptions, most liquids and solids have densities that range from about 0.7 g/cm3 (the density of gasoline) to 19 g/cm3 (the density of gold). The density of air is about 1.2 g/L. Table \(\PageIndex{3}\) shows the densities of some common substances.

    Table \(\PageIndex{3}\): Densities of Common Substances
    Solids Liquids Gases (at 25 °C and 1 atm)
    ice (at 0 °C) 0.92 g/cm3 water 1.0 g/cm3 dry air 1.20 g/L
    oak (wood) 0.60–0.90 g/cm3 ethanol 0.79 g/cm3 oxygen 1.31 g/L
    iron 7.9 g/cm3 acetone 0.79 g/cm3 nitrogen 1.14 g/L
    copper 9.0 g/cm3 glycerin 1.26 g/cm3 carbon dioxide 1.80 g/L
    lead 11.3 g/cm3 olive oil 0.92 g/cm3 helium 0.16 g/L
    silver 10.5 g/cm3 gasoline 0.70–0.77 g/cm3 neon 0.83 g/L
    gold 19.3 g/cm3 mercury 13.6 g/cm3 radon 9.1 g/L

     

    Pressure

    Pressure is the measure of the force exerted on a unit area of surface. Its SI units are therefore newtons per square meter, but we make such frequent use of pressure that a derived SI unit, the pascal, is commonly used:

    1 Pa = 1 N m–2

     

    The concept of pressure first developed in connection with studies relating to the atmosphere and vacuum that were first carried out in the 17th century. The molecules of a gas are in a state of constant thermal motion, moving in straight lines until experiencing a collision that exchanges momentum between pairs of molecules and sends them bouncing off in other directions.

    The concept of pressure first developed in connection with studies relating to the atmosphere and vacuum that were first carried out in the 17th century. The molecules of a gas are in a state of constant thermal motion, moving in straight lines until experiencing a collision that exchanges momentum between pairs of molecules and sends them bouncing off in other directions. This leads to a completely random distribution of the molecular velocities both in speed and direction— or it would in the absence of the Earth’s gravitational field which exerts a tiny downward force on each molecule, giving motions in that direction a very slight advantage. In an ordinary container this effect is too small to be noticeable, but in a very tall column of air the effect adds up: the molecules in each vertical layer experience more downward-directed hits from those above it. The resulting force is quickly randomized, resulting in an increased pressure in that layer which is then propagated downward into the layers below.

     

    The Barometer

    In the early 17th century, the Italian physicist and mathematician Evangalisto Torricelli invented a device to measure atmospheric pressure. The Torricellian barometer consists of a vertical glass tube closed at the top and open at the bottom. It is filled with a liquid, traditionally mercury, and is then inverted, with its open end immersed in the container of the same liquid. The liquid level in the tube will fall under its own weight until the downward force is balanced by the vertical force transmitted hydrostatically to the column by the downward force of the atmosphere acting on the liquid surface in the open container. Torricelli was also the first to recognize that the space above the mercury constituted a vacuum, and is credited with being the first to create a vacuum.

     

    One standard atmosphere will support a column of mercury that is 76 cm high, so the “millimeter of mercury”, now more commonly known as the torr, has long been a common pressure unit in the sciences: 1 atm = 760 torr.

    \[1\, \text{Pa} = 1\, \text{N}\, \text{m}^{–2}\]

    Pressure of Earth's Atmosphere

    The molecules of gas in Earth's atmosphere are in constant motion. This leads to a completely random distribution of the molecular velocities both in speed and direction— or it would in the absence of the Earth’s gravitational field which exerts a tiny downward force on each molecule, giving motions in that direction a very slight advantage. In an ordinary container this effect is too small to be noticeable, but in a very tall column of air the effect adds up: the molecules in each vertical layer experience more downward-directed hits from those above it. The resulting force is quickly randomized, resulting in an increased pressure in that layer which is then propagated downward into the layers below.  Figure \(\PageIndex{3}\)

     

    fig-ch01_patchfile_01.jpg
    Figure \(\PageIndex{3}\): Atmospheric Pressure. At sea level, the total mass of the sea of air pressing down on each 1-cm2 of surface is about 1034 g, or 10340 kg m–2. (Chem1 Lower)

    Add to attributions info = Chem1 Lower.  ccby4[ccby4l]  Stephen Lower

    At sea level, the total mass of the sea of air pressing down on each 1-cm2 of surface is about 1034 g, or 10340 kg m–2. The force (weight) that the Earth’s gravitional acceleration g exerts on this mass is

    \[\begin{align} f &= ma \nonumber \\[4pt] &= mg \nonumber \\[4pt] &= (10340\text{ kg})(9.81\text{ m s}^{–2}) \nonumber \\[4pt] &= 1.013 \times 10^5\text{ kg m s}^{–2} \nonumber \\[4pt] &= 1.013 \times 10^5 \text{ newtons} \end{align}\]

    resulting in a pressure of

    \[1.013 \times 10^5\, \text{N}\, \text{m}^{–2} = 1.013 \times 10^5 \text{ Pa}.\]

    The actual pressure at sea level varies with atmospheric conditions, so it is customary to define standard atmospheric pressure as 1 atm = 1.013105 pa or 101 kpa. Although the standard atmosphere is not an SI unit, it is still widely employed. In meteorology, the bar, exactly 1.000 × 105 = 0.967 atm, is often used.  Figure \(\PageIndex{4}\)

    fig-ch01_patchfile_01.jpg
    Figure \(\PageIndex{4}\): Range of Pressures. Pressure in atmospheres cover a long range of values in atmospheres depending on the situation. (Chem1 Lower)

     

    Non-SI Units

    There is a category of units that are “honorary” members of the SI in the sense that it is acceptable to use them along with the base units defined above. These include such mundane units as the hour, minute, and degree (of angle), etc., but the three shown here are of particular interest to chemistry, and you will need to know them.

    • liter (\(L\)) \[1\, L = 1\, dm^3 = 10^{–3} m^3 \nonumber\]
    • metric ton (\(t\)) \[1\, t = 10^3 kg \nonumber\]
    • atomic mass unit (\(u\)) \[1\, u = 1.66054×10^{–27}\, kg \nonumber\]

    Most of the physical quantities we actually deal with in science and also in our daily lives, have units of their own: volume, pressure, energy and electrical resistance are only a few of hundreds of possible examples. It is important to understand, however, that all of these can be expressed in terms of the SI base units; they are consequently known as derived units.

    Equations

    Constants of Proportionality

    Mathematical relationships such as Hubble’s law are pretty common in life. To take a simple example, suppose your college or university hires you to call rich alumni and ask for donations. You are paid $2.50 for each call; the more calls you can squeeze in between studying astronomy and other courses, the more money you take home. We can set up a formula that connects p, your pay, and n, the number of calls

    p=A×np=A×n

    where A is the alumni constant, with a value of $2.50. If you make 20 calls, you will earn $2.50 times 20, or $50.

    Suppose your boss forgets to tell you what you will get paid for each call. You can calculate the alumni constant that governs your pay by keeping track of how many calls you make and noting your gross pay each week. If you make 100 calls the first week and are paid $250, you can deduce that the constant is $2.50 (in units of dollars per call). Hubble, of course, had no “boss” to tell him what his constant would be—he had to calculate its value from the measurements of distance and velocity.

    Variables, constants, proportionality

    Equations - used in physics to simulate behavior of nature - predictive

    define variables and constants

    Directly and inversely proportional

    exponentials

    example problems

    Constants

    Do not delete tables! Attribution tag!

    Table E1: Physical Constants
    Name Value
    speed of light (c) 2.9979 × 108 m/s
    gravitational constant (G) 6.674 × 10−11 m3/(kg s2)
    Planck’s constant (h) 6.626 × 10−34 J-s
    mass of a hydrogen atom (MH) 1.673 × 10−27 kg
    mass of an electron (Me) 9.109 × 10−31 kg
    Rydberg constant (RR) 1.0974 × 107 m−1
    Stefan-Boltzmann constant (σ) 5.670 × 10−8 J/(s·m2 deg4)1
    Wien’s law constant (λmaxT) 2.898 × 10−3 m K
    electron volt (energy) (eV) 1.602 × 10−19 J
    energy equivalent of 1 ton TNT 4.2 × 109 J
    Table E2: Astronomical Constants
    Name Value
    astronomical unit (AU) 1.496 × 1011 m
    Light-year (ly) 9.461 × 1015 m
    parsec (pc) 3.086 × 1016 m = 3.262 light-years
    sidereal year (y) 3.156 × 107 s
    mass of Earth (MEarth) 5.974 × 1024 kg
    equatorial radius of Earth (REarth) 6.378 × 106 m
    obliquity of ecliptic 23° 26’
    surface gravity of Earth (g) 9.807 m/s2
    escape velocity of Earth (vEarth) 1.119 × 104 m/s
    mass of Sun (MSun) 1.989 × 1030 kg
    equatorial radius of Sun (RSun) 6.960 × 108 m
    luminosity of Sun (LSun) 3.85 × 1026 W
    solar constant (flux of energy received at Earth) (S) 1.368 × 103 W/m2
    Hubble constant (H0) approximately 20 km/s per million light-years, or approximately 70 km/s per megaparsec

    Examples and Exercises

    Example: Scientific Notation

    Scientific Notation

    In 2015, the richest human being on our planet had a net worth of $79.2 billion. Some might say this is an astronomical sum of money. Express this amount in scientific notation.
    Solution

    $79.2 billion can be written $79,200,000,000. Expressed in scientific notation it becomes \(\$7.92 \times 10^{10}\)

    Example: Light Years

    Getting Familiar with a Light Year

    How many kilometers are there in a light-year?
    Solution

    Light travels \(3 \times 10^5\) km in 1 s. So, let's calculate how far it goes in a year:

    • There are 60 \((6 \times 10^1)\) s in 1 min, and \(6 \times 10^1\) min in 1 h.
    • Multiply these together and you find that there are \(3.6 \times 10^3\) s/h.
    • Thus, light covers \(3 \times 10^5 \text{ km/s} \times 3.6 \times 10^3 \text{ s/h} = 1.08 \times 10^9 \text{ km/h}\).
    • There are 24 or \(2.4 \times 10^1\) h in a day, and 365.25 \((3.65 \times 10^2)\) days in 1 y.
    • The product of these two numbers is \(8.77 \times 10^3\) h/y.
    • Multiplying this by \(1.08 \times 10^9\) km/h gives \(9.46 \times 10^{12}\) km/light-year.

    That's almost 10,000,000,000,000 km that light covers in a year. To help you imagine how long this distance is, we'll mention that a string 1 light-year long could fit around the circumference of Earth 236 million times.

    Further Exploration

    Further Exploration


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