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Physics LibreTexts

19.10: Hydrogen Bonding

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Structure of nitrogen gas Figure 19.10.1 (CC BY-NC-SA 3.0; Molecule Public Domain; CK-12 Foundation - Joy Sheng, using 3D molecular structure by Ben Mills (Wikimedia: Benjah-bmm27) via Molecular structure: http://commons.wikimedia.org/wiki/File:Nitrogen-3D-vdW.png) Structure of ammonia Figure 19.10.2 (Public Domain; (Left) User:Booyabazooka/Wikimedia Commons; (Right) Ben Mills (Wikimedia: Benjah-bmm27) via (Left) http://commons.wikimedia.org/wiki/File:Ammonia_lone_electron_pair.svg; (Right) http://commons.wikimedia.org/wiki/File:Ammonia-3D-balls-A.png)

What's the difference between these two molecules?

A rough rule of thumb is that higher molecular-weight materials have higher boiling points than their lower molecular-weight counterparts. More energy is needed to move the larger molecule from the liquid state to the vapor state. However, ammonia has a boiling point of 33.34oC and a molecular weight of 17, while nitrogen (molecular weight 28) has a boiling point of 195.8oC. The lighter ammonia molecule must have other factors that influence its physical properties.

Hydrogen Bonding

The attractive force between water molecules is a dipole interaction. The hydrogen atoms are bound to the highly electronegative oxygen atom (which also possesses two lone pair sets of electrons, making for a very polar bond). The partially positive hydrogen atom of one molecule is then attracted to the oxygen atom of a nearby water molecule (see figure below).

Diagram of two water molecules showing hydrogen bonding. Oxygen atoms are labeled δ- and hydrogen atoms δ+. The dotted line represents the hydrogen bond between the molecules. Figure 19.10.3: A hydrogen bond in water occurs between the hydrogen atom of one water molecule and the lone pair of electrons on an oxygen atom of a neighboring water molecule. (Public Domain; Ben Mills (Wikimedia: Benjah-bmm27) via Wikipedia)

A hydrogen bond is an intermolecular attractive force in which a hydrogen atom that is covalently bonded to a small, highly electronegative atom is attracted to a lone pair of electrons on an atom in a neighboring molecule. Hydrogen bonds are very strong compared to other dipole interactions. The strength of a typical hydrogen bond is about 5% of that of a covalent bond.

Hydrogen bonding occurs only in molecules where hydrogen is covalently bonded to one of three elements: fluorine, oxygen, or nitrogen. These three elements are so electronegative that they withdraw the majority of the electron density in the covalent bond with hydrogen, leaving the H atom very electron-deficient. The H atom nearly acts as a bare proton, leaving it very attracted to lone pair electrons on a nearby atom.

The hydrogen bonding that occurs in water leads to some unusual, but very important, properties. Most molecular compounds that have a mass similar to water are gases at room temperature. Because of the strong hydrogen bonds, water molecules are able to stay condensed in the liquid state. The figure below shows how the bent shape, and two hydrogen atoms per molecule, allows each water molecule to be able to hydrogen bond to two other molecules.

Diagram showing water molecules with partial charges. Oxygen atoms are red, hydrogen atoms are gray. Dashed lines indicate hydrogen bonds between molecules. Figure 19.10.4: Multiple hydrogen bonds occur simultaneously in water because of its bent shape and the presence of two hydrogen atoms per molecule. (CC BY-NC 3.0; Laura Guerin via CK-12 Foundation)

In the liquid state, the hydrogen bonds of water can break and reform as the molecules flow from one place to another. When water is cooled, the molecules begin to slow down. Eventually, when water is frozen to ice, the hydrogen bonds become permanent and form a very specific network (see figure below).

Diagram of a water molecule lattice structure showing red oxygen atoms bonded to white hydrogen atoms in a repeating geometric pattern, illustrating ices crystalline form. Figure 19.10.5: When water freezes to ice, the hydrogen bonding network becomes permanent. Each oxygen atom has an approximately tetrahedral geometry—two covalent bonds and two hydrogen bonds. (Public Domain; User:Materialscientist/Wikimedia Commons via Wikipedia)

The bent shape of the molecules leads to gaps in the hydrogen bonding network of ice. Ice has a very unusual property—its solid state is less dense than its liquid state. Ice floats in water. Virtually all other substances are denser in the solid state than in the liquid state. Hydrogen bonds play a very important biological role in the physical structures of proteins and nucleic acids.

Simulation

Why does water form droplets? Hint: it has to do with the attraction between water molecules. Learn more (and see how many drops of water you can get a penny can hold) in this simulation.

Summary

  • Hydrogen bonds form when a H attached to a N, O, or F atom interacts with another N, O, or F atom.

Review

  1. How strong is a hydrogen bond?
  2. What happens when H is covalently bonded to N, O, or F?
  3. How does the shape of the water molecule affect the properties of ice?

This page titled 19.10: Hydrogen Bonding is shared under a CK-12 license and was authored, remixed, and/or curated by CK-12 Foundation via source content that was edited to the style and standards of the LibreTexts platform.

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