8.E: Central Potentials (Exercises)
- Page ID
- 15775
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)- A particle of mass \(m\) is placed in a finite spherical well:
\[V(r) = \left\{ \begin{array}{lcl} -V_0&\mbox{\hspace{1cm}}&\mbox{for $r\leq a$}\\ 0&&\mbox{for $r>a$} \end{array} \right. , \nonumber \]
with \(V_0>0\) and \(a>0\). Find the ground-state by solving the radial equation with \(l=0\). Show that there is no ground-state if \(V_0\,a^2< \pi^2\,\hbar^2/(8\,m)\).
- Consider a particle of mass \(m\) in the three-dimensional harmonic oscillator potential \(V(r)=(1/2)\,m\,\omega^2\,r^2\). Solve the problem by separation of variables in spherical coordinates, and, hence, determine the energy eigenvalues of the system.
- The normalized wavefunction for the ground-state of a hydrogen-like atom (neutral hydrogen, \({\rm He}^+\), \({\rm Li}^{++}\), et cetera.) with nuclear charge \(Z\,e\) has the form
\[\psi = A\,\exp(-\beta\,r), \nonumber \]
where \(A\) and \(\beta\) are constants, and \(r\) is the distance between the nucleus and the electron. Show the following:
- \(A^2=\beta^{\,3}/\pi\).
- \(\beta = Z/a_0\), where \(a_0=(\hbar^2/m_e)\,(4\pi\,\epsilon_0/e^2)\).
- The energy is \(E=-Z^2\,E_0\) where \(E_0 = (m_e/2\,\hbar^2)\,(e^2/4\pi\,\epsilon_0)^2\).
- The expectation values of the potential and kinetic energies are \(2\,E\) and \(-E\), respectively.
- The expectation value of \(r\) is \((3/2)\,(a_0/Z)\).
- The most probable value of \(r\) is \(a_0/Z\).
- An atom of tritium is in its ground-state. Suddenly the nucleus decays into a helium nucleus, via the emission of a fast electron that leaves the atom without perturbing the extranuclear electron, Find the probability that the resulting \({\rm He}^+\) ion will be left in an \(n=1\), \(l=0\) state. Find the probability that it will be left in a \(n=2\), \(l=0\) state. What is the probability that the ion will be left in an \(l>0\) state?
- Calculate the wavelengths of the photons emitted from the \(n=2\), \(l=1\) to \(n=1\), \(l=0\) transition in hydrogen, deuterium, and positronium.
- To conserve linear momentum, an atom emitting a photon must recoil, which means that not all of the energy made available in the downward jump goes to the photon. Find a hydrogen atom’s recoil energy when it emits a photon in an \(n=2\) to \(n=1\) transition. What fraction of the transition energy is the recoil energy?
- Show that the most probable value of \(r\) in the hydrogen ground state is \(a_0\).
- Let \(R_{nl}(r)= v_{nl}(r/a_0)/(r/a_0)\), where \(R_{nl}(r)\) is a properly normalized radial hydrogen wavefunction corresponding to the conventional quantum numbers \(n\) and \(l\), and \(a_0\) is the Bohr radius. [ex4 .fgh]
- Demonstrate that
\[\frac{d^2v_{nl}}{dy^2} = \left[\frac{l\,(l+1)}{y^2} -\frac{2}{y} + \frac{1}{n^2}\right]v_{nl}. \nonumber \]
- Show that \(v_{nl}\sim y^{\,1+l}\) in the limit \(y\rightarrow 0\).
- Demonstrate that
\[\left(\frac{1}{n^2}-\frac{1}{m^2}\right)\int_0^\infty v_{nl}(y)\,v_{ml}(y)\,dy = 0. \nonumber \]
- Hence, deduce that
\[\int_0^\infty r^2\,R_{nl}(r)\,R_{ml}(r)\,dr=0 \nonumber \]
for \(n\neq m\).
- Demonstrate that


