8.S: Atomic Structure (Summary)
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Key Terms
angular momentum orbital quantum number (l) | quantum number associated with the orbital angular momentum of an electron in a hydrogen atom |
angular momentum projection quantum number (m) | quantum number associated with the z-component of the orbital angular momentum of an electron in a hydrogen atom |
atomic orbital | region in space that encloses a certain percentage (usually 90%) of the electron probability |
Bohr magneton | magnetic moment of an electron, equal to 9.3×10−24J/T or 5.8×10−5eV/T |
braking radiation | radiation produced by targeting metal with a high-energy electron beam (or radiation produced by the acceleration of any charged particle in a material) |
chemical group | group of elements in the same column of the periodic table that possess similar chemical properties |
coherent light | light that consists of photons of the same frequency and phase |
covalent bond | chemical bond formed by the sharing of electrons between two atoms |
electron configuration | representation of the state of electrons in an atom, such as 1s22s1 for lithium |
fine structure | detailed structure of atomic spectra produced by spin-orbit coupling |
fluorescence | radiation produced by the excitation and subsequent, gradual de-excitation of an electron in an atom |
hyperfine structure | detailed structure of atomic spectra produced by spin-orbit coupling |
ionic bond | chemical bond formed by the electric attraction between two oppositely charged ions |
laser | coherent light produced by a cascade of electron de-excitations |
magnetic orbital quantum number | another term for the angular momentum projection quantum number |
magnetogram | pictoral representation, or map, of the magnetic activity at the Sun’s surface |
metastable state | state in which an electron “lingers” in an excited state |
monochromatic | light that consists of photons with the same frequency |
Moseley plot | plot of the atomic number versus the square root of X-ray frequency |
Moseley’s law | relationship between the atomic number and X-ray photon frequency for X-ray production |
orbital magnetic dipole moment |
measure of the strength of the magnetic field produced by the orbital angular momentum of the electron |
Pauli’s exclusion principle | no two electrons in an atom can have the same values for all four quantum numbers (n,l,m,ms) |
population inversion | condition in which a majority of atoms contain electrons in a metastable state |
principal quantum number (n) | quantum number associated with the total energy of an electron in a hydrogen atom |
radial probability density function | function use to determine the probability of a electron to be found in a spatial interval in r |
selection rules | rules that determine whether atomic transitions are allowed or forbidden (rare) |
spin projection quantum number (ms) | quantum number associated with the z-component of the spin angular momentum of an electron |
spin quantum number (s) | quantum number associated with the spin angular momentum of an electron |
spin-flip transitions | atomic transitions between states of an electron-proton system in which the magnetic moments are aligned and not aligned |
spin-orbit coupling | interaction between the electron magnetic moment and the magnetic field produced by the orbital angular momentum of the electron |
stimulated emission | when a photon of energy triggers an electron in a metastable state to drop in energy emitting an additional photon |
transition metal | element that is located in the gap between the first two columns and the last six columns of the table of elements that contains electrons that fill the d subshell |
valence electron | electron in the outer shell of an atom that participates in chemical bonding |
Zeeman effect | splitting of energy levels by an external magnetic field |
Key Equation
Orbital angular momentum | L=√l(l+1)ℏ |
z-component of orbital angular momentum | Lz=mℏ |
Radial probability density function | P(r)dr=∣ψn00∣24πr2dr |
Spin angular momentum | S=√s(s+1)ℏ |
z-component of spin angular momentum | Sz=msℏ |
Electron spin magnetic moment | →μs=(eme)→S |
Electron orbital magnetic dipole moment | →μ=−(e2me)→L |
Potential energy associated with the magnetic interaction between the orbital magnetic dipole moment and an external magnetic field vecB | U(θ)=−μzB=mμBB |
Maximum number of electrons in a subshell of a hydrogen atom | N=4l+2 |
Selection rule for atomic transitions in a hydrogen-like atom | Δl=±1 |
Moseley’s law for X-ray production | (Z−1)=constant√f |
Summary
8.1 The Hydrogen Atom
- A hydrogen atom can be described in terms of its wave function, probability density, total energy, and orbital angular momentum.
- The state of an electron in a hydrogen atom is specified by its quantum numbers (n, l, m).
- In contrast to the Bohr model of the atom, the Schrödinger model makes predictions based on probability statements.
- The quantum numbers of a hydrogen atom can be used to calculate important information about the atom.
8.2 Orbital Magnetic Dipole Moment of the Electron
- A hydrogen atom has magnetic properties because the motion of the electron acts as a current loop.
- The energy levels of a hydrogen atom associated with orbital angular momentum are split by an external magnetic field because the orbital angular magnetic moment interacts with the field.
- The quantum numbers of an electron in a hydrogen atom can be used to calculate the magnitude and direction of the orbital magnetic dipole moment of the atom.
8.3 Electron Spin
- The state of an electron in a hydrogen atom can be expressed in terms of five quantum numbers.
- The spin angular momentum quantum of an electron is = +½. The spin angular momentum projection quantum number is \(\displaystyle ms =+½\) or −½ (spin up or spin down).
- The fine and hyperfine structures of the hydrogen spectrum are explained by magnetic interactions within the atom.
8.4 The Exclusion Principle and the Periodic Table
- Pauli’s exclusion principle states that no two electrons in an atom can have all the same quantum numbers.
- The structure of the periodic table of elements can be explained in terms of the total energy, orbital angular momentum, and spin of electrons in an atom.
- The state of an atom can be expressed by its electron configuration, which describes the shells and subshells that are filled in the atom.
8.5 Atomic Spectra and X-rays
- Radiation is absorbed and emitted by atomic energy-level transitions.
- Quantum numbers can be used to estimate the energy, frequency, and wavelength of photons produced by atomic transitions.
- Atomic fluorescence occurs when an electron in an atom is excited several steps above the ground state by the absorption of a high-energy ultraviolet (UV) photon.
- X-ray photons are produced when a vacancy in an inner shell of an atom is filled by an electron from the outer shell of the atom.
- The frequency of X-ray radiation is related to the atomic number Z of an atom.
8.6 Lasers
- Laser light is coherent (monochromatic and “phase linked”) light.
- Laser light is produced by population inversion and subsequent de-excitation of electrons in a material (solid, liquid, or gas).
- CD and Blu-Ray players uses lasers to read digital information stored on discs.